![]() Ionic compounds that contain water molecules as integral components of their crystals are called hydrates. ![]() The other fluoride of tin is SnF 4, which was previously called stannic fluoride but is now named tin(IV) fluoride. This represents the formula SnF 2, which is more properly named tin(II) fluoride. For example, you may see the words stannous fluoride on a tube of toothpaste. Though this naming convention has been largely abandoned by the scientific community, it remains in use by some segments of industry. Out-of-date nomenclature used the suffixes – ic and – ous to designate metals with higher and lower charges, respectively: Iron(III) chloride, FeCl 3, was previously called ferric chloride, and iron(II) chloride, FeCl 2, was known as ferrous chloride. Other examples are provided in Table 2.9. These two compounds are then unambiguously named iron(II) chloride and iron(III) chloride, respectively. In cases like this, the charge of the metal ion is included as a Roman numeral in parentheses immediately following the metal name. The simplest name, “iron chloride,” will, in this case, be ambiguous, as it does not distinguish between these two compounds. Iron typically exhibits a charge of either 2+ or 3+ (see Figure 2.29), and the two corresponding compound formulas are FeCl 2 and FeCl 3. For example, consider binary ionic compounds of iron and chlorine. The charge of the metal ion is determined from the formula of the compound and the charge of the anion. Compounds of these metals with nonmetals are named with the same method as compounds in the first category, except the charge of the metal ion is specified by a Roman numeral in parentheses after the name of the metal. Most of the transition metals and some main group metals can form two or more cations with different charges. Table 2.8 Compounds Containing a Metal Ion with a Variable Charge The name of a binary compound containing monatomic ions consists of the name of the cation (the name of the metal) followed by the name of the anion (the name of the nonmetallic element with its ending replaced by the suffix – ide). First, is the compound ionic or molecular? If the compound is ionic, does the metal form ions of only one type (fixed charge) or more than one type (variable charge)? Are the ions monatomic or polyatomic? If the compound is molecular, does it contain hydrogen? If so, does it also contain oxygen? From the answers we derive, we place the compound in an appropriate category and then name it accordingly. ![]() To name an inorganic compound, we need to consider the answers to several questions. The rules for organic compounds, in which carbon is the principle element, will be treated in a later chapter on organic chemistry. We will limit our attention here to inorganic compounds, compounds that are composed principally of elements other than carbon, and will follow the nomenclature guidelines proposed by IUPAC. The simplest of these are binary compounds, those containing only two elements, but we will also consider how to name ionic compounds containing polyatomic ions, and one specific, very important class of compounds known as acids (subsequent chapters in this text will focus on these compounds in great detail). This module describes an approach that is used to name simple ionic and molecular compounds, such as NaCl, CaCO 3, and N 2O 4. Nomenclature, a collection of rules for naming things, is important in science and in many other situations. Derive names for common types of inorganic compounds using a systematic approach.By the end of this section, you will be able to:
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![]() The same thing happens when I put my data connection on and opens the app: it just goes out of function for a while. Nothings gonna work for about 5 minutes and it’s frustrating. Anytime I send a status update or delete one my WhatsApp goes out of service, it just hangs and you can’t click anything at all. But it’s got a few bugs that we’ve got to fix up. We're always excited to hear from you! If you have any feedback, questions, or concerns, please email us at Gorgįirst and foremost I’d like to say a huge and fantastic thank you for creating such a resourceful app, it’s the best thing for businesses out there at the moment. WhatsApp Business is built on top of WhatsApp Messenger and includes all the features that you rely on, such as the ability to send multimedia, free calls*, free international messaging*, group chat, offline messages, and much more.
![]() You can also share through Facebook, Twitter and email. Publish your work to the Behance creative community and get feedback without leaving the app. Incorporate quality imagery into your work. Start your creative work on any device and seamlessly pick it up on another. Photoshop Illustrator Capture Photoshop Sketch You can also take advantage of other Creative Cloud services like: ADOBE STOCK Search for and license high-res, royalty-free images from inside Draw. Get easy in-app access to your assets - including Adobe Stock images, photos you processed in Lightroom, or scalable vector-based shapes created in Capture.Īdobe CreativeSync ensures that your files, fonts, design assets, settings and more all instantly appear in your workflow wherever you need them. ![]() ![]() Search for and license high-res, royalty-free images from inside Draw. You can also take advantage of other Creative Cloud services like: Send an editable native file to Illustrator or a PSD to Photoshop that automatically opens on your desktop.Read more Old Versions Adobe Illustrator Draw 3.7.29 APK Android 9.0+ Adobe Illustrator Draw 3.7.27 APK Android 9.0+ Adobe Illustrator Draw 3.7.22 APK Android 9. Insert basic shape stencils or new vector shapes from Capture. Install Adobe Illustrator Draw APK on Android Tap Adobe Illustrator Draw.apk.Rename, duplicate, merge and adjust each individual layer.Work with multiple image and drawing layers.Sketch with five different pen tips with adjustable opacity, size and color.Illustrators, graphic designers and artists can: No matter what your goals are for the art you're drawing, Adobe Illustrator should prove to be a very useful tool.Winner of the Tabby Award for Creation, Design and Editing and PlayStore Editor’s Choice Award!Ĭreate vector artwork with image and drawing layers you can send to Adobe Illustrator or to Photoshop. You can access all the drawing and sketching tools on desktop and mobile. Whether you're an artist looking for a quick way to create graphics for websites or company brochures, or you're simply looking to make a unique drawing to give as a gift, you will be happy with the functionality of the Adobe Illustrator Draw app. Download SketchBook This full-feature version of SketchBook is free for everyone. This makes it very easy to switch between tools, draw new shapes, and perform other basic functions without having to navigate away from the keyboard.Įven if you're not someone who feels particularly comfortable drawing on the go, you'll find that this program is extremely easy to use. When you choose to continue, you'll find that the buttons for the draw features are located within the design section of the main menu. You tap these buttons to launch the app, and the design software will then prompt you to start a new project. On the regular version you will find a large home button on the lower right-hand corner of the screen, and another button that opens the Adobe Illustrator Draw app. The biggest difference between the regular version and the touch-screen version of the program is the size and appearance of the on-screen buttons. Luckily, the program is really easy to learn and gets you pointed in the right direction quickly. ![]() If you're used to working with the pen and paper version, you may feel a bit lost at first. One of the most important pieces of information you need to be aware of, however, is that the touch-screen version of this program does not include a drawing wizard. If you've used Adobe Illustrator before, or are just thinking about trying out this particular program on your tablet or phone, you'll find that there are a few different things you should know. Unlike the regular version, this program allows you to draw on your Android device with an assortment of different tools from your keyboard. Adobe Illustrator Draws is basically a variation of Adobe's popular digital drawing program designed specifically for touch-screen devices such as the Android. ![]() ![]() “Some who judge only by appearances, make it consists in penances in hair shirts, austerities of the flesh, vigils, fasting, and similar bodily mortifications” Others, particularly women, fancy themselves extremely virtuous when they indulge in long vocal prayers, hear several Masses, spend many hours in Church, and frequently receive Communion” (Scupoli, Spiritual Combat). In the coming weeks, we shall explore the various teachings of Dom Scupoli as it concerns our need to grow in spiritual things, and begin to pay less attention to the externals of our religion. I am equally recommending this book to all those who would love to attain some level of perfection, peace of the soul, and a mastery of the spiritual life. St Francis de Sales (1576- 1622), Doctor of the Church and master of the spiritual life, read it every day and recommended it to everyone under his direction. The spiritual Combat first published in 1589, provides timeless guidance in spiritual discipline. Scupoli was a 16th century writer and mystic who was born in Otranto, Italy in 1530 and died in Naples in 1610. In the course of my readings lately, I came across the works of Dom Lorenzo Scupoli, titled: The Spiritual Combat and A Treatise on the Peace of Soul. He indeed is perfect, as being omnipotent man, as being aided by the Omnipotent”. Saint Remigius (437 – 533) said, “because the utmost perfection of love cannot go beyond the love of enemies, therefore as soon as the Lord has bid us love our enemies, He proceeds, ‘Be ye then perfect, as your Father which is in heaven is perfect’. If you love those who love you, what reward will you get? Are not even the tax collectors doing that? And if you greet only your own people, what are you doing more than others? Do not even pagans do that? Be perfect, therefore, as your heavenly Father is perfect” (Matthew 5: 43-48). He causes his sun to rise on the evil and the good, and sends rain on the righteous and the unrighteous. “You have heard that it was said, ‘Love your neighbour and hate your enemy.’ But I tell you, love your enemies and pray for those who persecute you, that you may be children of your Father in heaven. ![]() If you want to learn to groom a dog at home, a Cavalier will probably be one of the most patient breeds you could choose to practice on. ![]() You don’t trim your pup if you don’t want to, but if you do, consider one of the adorable styles on our list.Ĭavalier King Charles Spaniels are one of the most popular breeds in the country, thanks in large part to their laid-back, gentle personalities. Check your dog’s eyes regularly for any colored discharge, squinting, or redness.Ĭompared to many breeds, keeping a Cavalier well-groomed is relatively simple. Tooth brushing once a day, you can start your Cavalier out by brushing its teeth with a childrens. Cavaliers are also prone to several eye conditions. Grooming Tips for Cavalier King Charles Spaniels Teeth. If your dog’s ears have a strong odor, discharge, redness, or seem painful, take them to the vet to be checked out. To help prevent these, clean your dog’s ears weekly, monitoring for any signs of infection when you do. Like other breeds with long, floppy ears, Cavaliers are prone to ear infections. If not, it’s very easy for hair fur to collect burs and other debris or become caked with mud, leading to irritation. Unless you choose to keep your dog shaved down short, expect to spend time brushing them as often as every day during the shedding season.Įven if you keep your dog’s coat natural with no trimming, keep the hair between their paw pads shaved down. Here is a photo of some of the essential grooming items mentioned above, with link suggestions where you can order.Tips for Grooming Your Cavalier King Charles SpanielĬavalier King Charles Spaniels have a double coat that can easily become matted and tangled without proper care. Cavalier King Charles Spaniels need daily brushing with a medium-bristle brush to stimulate and spread the skins natural oils throughout the coat. I suggest the Chris Christianson Oval Pin Brush with 27 mm pins, the Chris Christianson Medium texture boar brush to finish the top coat, and the “mini” Warner Slicker for the ears and hocks, as well as a 6″ comb. There are lots of quality grooming items to choose from. A grooming table would also be wonderful if it’s in the budget! You can find these in pet stores, but the better quality grooming items are usually found online in specialty stores ( see links below). You will need a good quality Comb, Slicker Brush, Pin brush, grooming spray, toothbrush and toothpaste appropriate for dogs, and nail clippers. Many owners find that bathing their pets every two months is quite adequate.” ![]() Brush Daily You should brush your Cavalier King Charles spaniel’s coat daily or at least several times a week. GROOMING TRAINING Easy to train Low levels of Quite easy to train Not so easy. The 5 Tips on How to Groom a Cavalier King Charles Spaniel 1. All knots and tangles should be brushed out before a Cavalier is bathed. Cavalier King Charles Spaniel Fox Terrier (Wire) Lakeland Terrier Suitable. Because too much bathing dries out the skin and haircoat, they should not be bathed more than once a week. No other trimming is necessary (or allowed) in the show ring.Ĭavaliers are naturally clean dogs. For medium and long coats, you will need to keep the knots in the shape of the ears, chest, back of the legs, tail, and lower base. Their nails should be clipped and the hair between their pads trimmed once a month. Ears need particular attention and should be checked and given a quick combing every few days, daily in shedding season.Ĭavaliers do shed, particularly in spring and fall, but a little all the time. Equipped with the best grooming brush for your pet’s needs, the daily brushing routine can be less stressful for you both. The thumbprint on a Cavalier King Charles Spaniel is a distinguishing feature and is used to help. Keeping your Cavalier King Charles Spaniel’s coat clean and healthy requires regular attention and brushing, however, this needn’t be a difficult task. ![]() It is usually found on the left side of the dog’s chest or abdomen and is thought to be a result of a gene mutation. These dogs are excellent pets because they are intelligent and get along well with humans and children. A thumbprint on a Cavalier King Charles Spaniel is a unique marking found on the dog’s coat that is shaped like a thumbprint. Moderate Maintenance:Â A comb and soft slicker brush should help to keep this breedâ s long coat in top shape. Knots and tangles are kept to a minimum if the Cavalier is free of parasites and combed regularly. The Cavalier King Charles Spaniel is a sweet, affectionate dog breed, and people love these dogs for their friendliness. From the opinion of expert Cavalier King Charles Spaniel dog groomers, Cavalier King Charles Spaniel dogs score out of 5 in a scale of dog breeds that require frequent grooming. A great deal of time and effort is not necessary if the dog is brushed and combed thoroughly at least once a week. “The Cavalier does require regular grooming. The following text is from the Cavalier King Charles Spaniel USA website: ![]() ![]() MediaMath sets this cookie to avoid the same ads from being shown repeatedly and for relevant advertising.Ī cookie set by YouTube to measure bandwidth that determines whether the user gets the new or old player interface. The test_cookie is set by and is used to determine if the user's browser supports cookies. Google DoubleClick IDE cookies are used to store information about how the user uses the website to present them with relevant ads and according to the user profile. This cookie is set by Facebook to display advertisements when either on Facebook or on a digital platform powered by Facebook advertising, after visiting the website. These cookies track visitors across websites and collect information to provide customized ads. It does not store any personal data.Īdvertisement cookies are used to provide visitors with relevant ads and marketing campaigns. 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Necessary cookies are absolutely essential for the website to function properly. ![]() ![]() sign in Create New Account Forgot your password Learn More Add to Phone. Phase 2 will begin at the start of Advent term (September 2023) and will allow My School Portal to replace our current ParentMail system, which will then be retired. Link your students and start monitoring things like grades, test scores, attendance. Make a payment to your students accounts with your credit. We provide the specific level and type of instruction and support for your student’s unique and evolving needs, challenges, and learning style. A quick link to our School Sports system Add your students using their school name and student ID (have the ID numbers handy when you log in).A quick link to our Parents’ Evening system.School reports (we will no longer be sending by post).Phase 1 will occur at the start of Trinity term (April 2023) and will allow parents to view their children's: The system is called My School Portal and it has been. Our intention is to roll the system out in two phases, to allow for an effective transition and so that we can fix any teething problems in a manageable way. We are delighted to announce that we are introducing a new parent communications platform to LGS and LGJS. We have been trialling My School Portal this term and we are really pleased with its functionality. Once it is fully implemented it will be a one-stop-shop through which you will be able to manage many of your interactions with the school. Elementary, middle, high school up to college age students can. The system is called My School Portal and it has been designed to streamline communications between school and parents, by bringing information and services together into one easy-to-use dashboard. ![]() We are delighted to announce that we are introducing a new parent communications platform to LGS and LGJS. Welcome to Leicester Grammar School's My School Portal page. ![]() Get the freedom to choose with Gina's four funky layout options: Standard, Southpaw, Ortholinear Standard, and Ortholinear Southpaw. Whether you're a gamer, streamer, accountant or Jeff Bezos, there's a Gina for you! With multiple layouts, saucy mount style, and sound-dampening cuts, Gina is not just a numpad-it's a game-changer! ⌨️ Pick Your Typing Adventure: Unique Layouts Crafted to fit snugly with 60% and 65% form factor keyboards, Gina is your trusty sidekick in typing. Meet Gina, the incredibly versatile Macro-Numpad by KeebCats. As needed, open the CUI Editor to make changes to the custom command and its macro, or create new macros based on your needs.□ Gina Macro-Numpad by KeebCats: Unleash Your Typing Superpowers!.Click the new button on the QAT to test the macro.Click OK to save the changes and exit the CUI Editor.When you see the cursor change to an arrow with a rectangle, release the mouse button to add the new command and shift the existing button to the right.Move the mouse pointer over top of an existing button or control on the toolbar.Click and drag the command onto the Quick Access toolbar (QAT) at the top of the AutoCAD application window.In the Customize User Interface (CUI) Editor, under the Commands pane, select the command you just created.Now that you have created a command with the recommended macro, the following steps explain how to add the custom command to the Quick Access toolbar: Click in the Large Image field and enter.Custom icons should be 16x16 or 32x32 pixels in size. You can also choose a custom icon by clicking the Ellipsis button. You can use the Button Image pane to find the name of one of the icons that ship with AutoCAD. RCDATA_16_COPYOB is the name of the icon assigned to the COPY command. Click in the Small Image field and enter.Click OK to exit the Long String Editor dialog box.Macro string: ^C^CDIMLAYER – Replace this string with the dimension style you frequently assign to your dimensions Sets a layer and dimension style current before creating a linear dimension.ĭefines the layer which new dimensions are to be placed and then sets a dimension style current before starting the Macro string: ^C^C._MOCORO \\ \_C \ _R \ Add Linear Dimension MOCORO command to simplify the transition of copying and then rotating the previously selected objects. Here are the macros you might see as recommendations:Ĭopies and then rotates the selected objects. The current list of macro recommendations is rather small, since this is currently a working idea to gauge interest and understand the direction in which to proceed. Using a Recommended Command Macro section for how to use the macro recommendation. If viewing insights in the Autodesk Account portal or My Insights email, see the Using a Recommended Action Macro section for how to use the macro recommendation. If viewing insights in-product (starting with AutoCAD 2022 Update 1), see the When a macro recommendation is made, you will see one of these versions of the insight based on the delivery channel from which the insight is viewed: Command Macros – Defined in a customization (CUIx) file with the Customize User Interface (CUI) Editor and then added to the AutoCAD user interface as a button on a ribbon tab or the Quick Access toolbar (QAT).When loaded, an action macro can be played back from the Action Recorder or by entering its name at the Command prompt. Action Macros – Recorded using the Action Recorder and saved to an action macro (ACTM) file.After that, theĭIMLINEAR command is started to create a linear dimension on the specific layer and with the specific style.Ĭommand sequences can be formatted into what are known as LAYER command is used to set a current layer, followed by the setting a dimension style current. ROTATE command used to rotate the previously copied objects. Here are a couple examples of command sequences:ĬOPY command used to copy objects followed by the These insights are based on the frequency in which you use specific sequences of commands. Macro recommendation insights can help you reduce repetitive tasks, enforce CAD standards, and simplify workflows by executing multiple commands, along with expected options and values. ![]() The Chiefs tied for the fewest takeaways with the Eagles. ![]() The Chiefs were 20th in total defense and 25th in points allowed. ![]() ![]() They were 23rd in total offense, 32nd in points scored, and 37 giveaways, tied for worst in the NFL. The Chiefs finished near the bottom of the league in most major statistical categories. In Week 17, the Chiefs matched the 1981 Baltimore Colts season record of losing 9 games by 14 points or more in one season as the Chiefs lost to Denver. In Week 16, the team rushed for a franchise record of 352 yards against the Colts and still lost the game. They wore black to games to protest and hired an airplane to fly over Arrowhead Stadium on game days towing a banner that read, "Restore Hope: Fire Pioli." When asked why running back Jamaal Charles carried the ball only 5 times in a week 8 loss to the Oakland Raiders, Romeo Crennel responded "Now, that I'm not exactly sure, either." In Week 15, the Chiefs didn't have a first down until the third quarter in a loss against Oakland. Fans formed the "Save Our Chiefs" organization. Chiefs tackle Eric Winston claimed Kansas City hometown fans cheered the injury of quarterback Matt Cassel in a Week 5 loss to the Baltimore Ravens calling it "Sick", however fans claim it was because Brady Quinn was seen coming onto the field and were cheering for him. In Week 4, the Chiefs had six turnovers in a loss to San Diego. The Chiefs broke the streak in Week 10 against the Pittsburgh Steelers when they led 10–0 in the second quarter before losing the game 16–13 in overtime. The Chiefs did defeat the Saints in week 3, but didn't lead until their game winning field goal in overtime. The Chiefs started the season tying the 1929 record of Buffalo Bisons for most games without ever leading in regulation (8 games). The Chiefs were tied with the Arizona Cardinals for most interceptions (20) with Matt Cassel throwing 12 and his late season replacement Brady Quinn throwing 8. Kansas City suffered from quarterback controversy all season. It was the second time in franchise history the Chiefs have had the #1 pick. The Chiefs had the number 1 pick in the 2013 National Football League Draft based on strength of schedule. They tied with the Jacksonville Jaguars for the NFL's worst record. The 20 seasons were the worst in terms of win percentage (.125) in franchise history. The 2012 team tied the 1977 (2–12) and 2008 (2–14) teams for the franchise worst seasons in terms of fewest wins. The Chiefs held a moment of silence for domestic violence victims and the teams met for a prayer on the field prior to the game. On December 1, 2012, the day before the Chiefs' week 13 game against the Carolina Panthers, linebacker Jovan Belcher murdered his girlfriend then drove to Arrowhead Stadium where he killed himself in front of Crennel and general manager Scott Pioli. The season remains, as of 2023, the most recent season that the Chiefs had a losing record. In 2017, named the 2012 season the Chiefs’ worst in franchise history. The Chiefs went 0–12 against AFC opponents in 2012 their only wins of the season were from NFC teams, against the Carolina Panthers and New Orleans Saints. Although they shared the same 2–14 record as the Jacksonville Jaguars for the worst record of the season, the Chiefs had a lower strength of schedule, so they were awarded the first pick in the 2013 NFL Draft. The Chiefs failed to rebound from their 7–9 record in 2011, and were eliminated from playoff contention in Week 12. The 2012 season was the Kansas City Chiefs' 43rd in the National Football League (NFL), their 53rd overall and their first and only full season under head coach Romeo Crennel, who had served as the interim head coach for the final three games of the 2011 season following Todd Haley's termination. ![]() Odds Shark has enlisted experts to help explain sports and poker odds, and casino pros who can advise on the math behind blackjack strategy. Odds Shark is THE place to research everything associated with betting odds and live lines. Whether you are betting the point spread, futures or runlines, learning about a sport’s odds should be one of your first focuses. Odds Shark shows you how the betting line is set, who sets the line, and why lines move during the week. Understanding betting odds is critical to becoming a successful sports bettor or at least giving yourself a better chance at winning pick’em pools and other contests. Why Make Odds Shark Your Home For Sports Wagering? 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In addition to more betting odds, there will be charts detailing how NFL OVER/UNDERs have moved during the week, and improved sports database functionality for all sports, including mixed martial arts (MMA) and tennis. ![]() And coming soon are line move histories, halftime odds and more tutorials on how to read - and beat - the NFL point spread. Looking for NFL consensus data on how Vegas is betting each game or NCAA football power rankings to help with your handicapping? It’s all here at Odds Shark. If you enjoy betting on football (on Saturdays or Sundays), we have you covered! Odds Shark’s Sports Betting Options We break down the action across every major event, specializing in football with betting lines, props and previews for NFL and college football fans alike. Odds Shark is the global authority for betting odds, tips and picks across sports, poker, casino games, politics, entertainment and much more. Video Poker Guide: Play the Best Online Video Poker Games. |
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